Having the Eye of Sulfuras to drop the first time I even tried to go for it was pretty stellar.
I was most excited to get my reins of the blue proto drake from skadi the ruthless. After four months of solid farming everyday I almost gave up. Said to myself "just one more" and that day, he dropped it.
After having solved 259 troll solves and leveling archeology for the soul purpose of getting Zin'rokh Destroyer of Worlds it finally appeared on my screen. I can still remember falling out of my chair with excitement.
Reins of the Raven Lord by far. After farming three months and finally getting it.
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Awesome :D
Getting Grand Marshal at lvl 60 and getting Ashes of Al'ar lastnight are the two things im most proud of achieving in my long wow career!
When I got my warglaives :D!
I have two that I can't choose between, both being in vanilla. First was getting an epic riding mount. 1000g was hard to come by when I only had about 10g at any given time. The second would have to be solo grinding Bloodsail Buccaneers to friendly and getting the pirate hat.
The most exciting thing that I achieved was the Feat of Strength "Insane in the Membrane" way back in wrath. This was pre-nerf, non-human. There were 2 other people in my guild competing against each other for the title and I had a funny idea: how bout I beat them to it and they didnt know I was working on it? I would farm Dire Maul during the night (yay summer break!) when everyone was sleeping. It was something like 450 DM runs for the goblins back then, what a pain. And sure enough the Darkmoon Faire came along one month and I beat them to it! I sure shocked them!
The thing I was happiest to get was Time-Lost Proto Drake. That happen today:)
I was happy when I finished What a Long, Strange Trip It's Been
Between all of the things i have acquired in game ranging from Thunderfury, the Warglaives, Thori'dal, Golad / Tiriosh, My hands down Favorites are my Swift Zulian Tiger and my Murky. I am extremely proud of my pets and mounts and all i can say is that a Mini Tyrael would make my collection of 343 pets even more Epic than it already is.